Compression-driven jamming in porous cohesive aggregates.
basic_science · Level V
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- Also identified by DOI 10.1039/d5sm00650c.
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Abstract
I investigate the compression-driven jamming behavior of two-dimensional porous aggregates composed of cohesive, frictionless disks. Three types of initial aggregates are prepared using different aggregation procedures, namely, reaction-limited aggregation (RLA), ballistic particle-cluster aggregation (BPCA), and diffusion-limited aggregation (DLA), to elucidate the influence of aggregate morphology. Using distinct-element-method simulations with a shrinking circular boundary, I numerically obtain the pressure as a function of the packing fraction <i>ϕ</i>. For the densest RLA and the intermediate BPCA aggregates, a clear jamming transition is observed at a critical packing fraction <i>ϕ</i><sub>J</sub>, below which the pressure vanishes and above which a finite pressure emerges; the transition is less distinct for the most porous DLA aggregates. The jamming threshold depends on the initial structure and, when extrapolated to infinite system size, approaches <i>ϕ</i><sub>J</sub> = 0.765 ± 0.004 for RLA, 0.727 ± 0.004 for BPCA, and 0.602 ± 0.023 for DLA, where the errors denote the standard error. Above <i>ϕ</i><sub>J</sub>, the pressure follows <i>P</i> ≈ <i>A</i>(<i>ϕ</i> - <i>ϕ</i><sub>J</sub>)<sup>2</sup>, which implies that the bulk modulus <i>K</i> of jammed aggregates is proportional to <i>ϕ</i> - <i>ϕ</i><sub>J</sub>. Rigid-cluster analysis of jammed aggregates shows that the average coordination number within the largest rigid cluster increases linearly with <i>ϕ</i> - <i>ϕ</i><sub>J</sub>. Taken together, these relations suggest that the elastic response of compressed porous aggregates is analogous to that of random spring networks.