Dynamic Reversible Full-Color Phosphorescence Afterglows from Stimuli-Responsive Carboxymethyl Chitosan Based Materials.
basic_science · Level V
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- Record sourced from PubMed, PMID 41457648.
- Also identified by DOI 10.1002/adma.202518820.
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Abstract
Pure organic stimuli-responsive persistent room-temperature phosphorescence (p-RTP) materials hold significant promise for encryption, bioimaging, sensing, and wearable optoelectronics. However, developing highly efficient smart p-RTP systems featuring full-color tunability and multi-dimensional reversible responsiveness remains a long-standing challenge, especially for nonconventional luminophores lacking significant conjugation. Herein, it is found that marine-derived carboxymethyl chitosan (CMCS) exhibits intrinsic excitation-tunable panchromatic (400-610 nm) photoluminescence (PL) and a record-high p-RTP quantum yield of 10.1% amongst nonconventional polymeric luminophores. Leveraging its outstanding PL, rigid conformation, and, moreover, inherent amino/carboxyl groups, we further construct a pyrenedicarboxylic acid salt-doped phosphorescence system that demonstrates efficient (8.8%), prolonged (515.1 ms), and dynamically tunable (495-710 nm) p-RTP with cyclable control via pH, delay time (t<sub>d</sub>), and excitation wavelength (λ<sub>ex</sub>). Moving beyond conventional aromatic structural modification strategies, this work achieves multimode stimuli-responsive and efficient p-RTP through the synergy between nonaromatic CMCS and aromatic chromophores, and the effective control of their intra/intermolecular interactions, chain conformation, and consequent dye aggregation, enabling versatile applications across anti-counterfeiting, encryption, information storage, and phosphorescent textiles.