Collective Rotation Mode in Lattice Migration under Electron Irradiation.
basic_science · Level V
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- Record sourced from PubMed, PMID 41536216.
- Also identified by DOI 10.1021/acs.nanolett.5c05767.
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Abstract
Understanding atomic migration dynamics is crucial for precise nanostructure synthesis and modification, particularly in beam-assisted phase engineering of nanomaterials. A universal nanoscale rotation mode has been observed during conventional <i>in situ</i> annealing and electron-beam irradiation. However, it remains poorly understood how the rotation mode is activated and drives nanoparticle migration and coalescence, particularly under electron-beam irradiation, where lattice rotation occurs even at room temperature. Here, using <i>in situ</i> transmission electron microscopy, we report a collective rotation mechanism induced by transient thermal spikes under electron irradiation. Our observations reveal that Pt and AuPt nanoparticles coalesce into larger islands with coherent {111} twin structures through nonrandom lattice rotation. We demonstrate that the observed rotation behavior fundamentally originates from asymmetric temperature gradients using molecular dynamics simulations and small-strain theory. These insights advance the understanding of nanocrystal migration dynamics under electron beam irradiation.