Heterophase fcc-hcp-fcc High-Entropy Alloy Nanomaterials with Tailored Electron Divergence for Selective Ammonia Electrosynthesis.

Meng, Xiang; Sun, Mingzi; Li, Xinyi; Chen, Jing; Wang, Yunhao; Hao, Fengkun; Liu, Fu; Zhao, Quanlin et al. · Adv Mater · 2026

basic_science · Level V

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Abstract

Electrocatalytic nitrate reduction reaction provides a broad prospect for developing green electrochemical ammonia production and efficient treatment of industrial wastewater rich in nitrate, but poses a challenge to the high activity and stability of electrocatalysts. Herein, we report the versatile and scalable one-pot solvothermal synthesis of a series of RuFeMMnMo (M═CoNi, Co, and Ni) high-entropy alloy (HEA) nanomaterials, possessing a unique face-centered cubic-hexagonal close-packed-face-centered cubic (fcc-hcp-fcc) heterophase. The highly random distribution of multiple metal components and the tunable diversity of metal atomic arrangements can be realized simultaneously. Significantly, RuFeCoNiMnMo HEAs present a high Faradaic efficiency of 99.3 % and a promising yield rate of 83.35 mg h<sup>-1</sup> mg<sub>cat</sub> <sup>-1</sup> toward ammonia production at -0.6 V vs. reversible hydrogen electrode. Ex/in situ characterizations and theoretical calculations have revealed that by high electron coupling of high-entropy effect, heterophase fcc-hcp-fcc RuFeCoNiMnMo HEAs have shown strong electronic modulations with charge redistributions. The positive charges and negative charges for Ru sites and Ni/Co sites promote the adsorption of key intermediates and generation of active protons, respectively, which guarantees efficient nitrate reduction due to the reduced energy barriers.