Chirality Switching in 1<i>T</i>-TaS<sub>2</sub> by Highly Charged Ion Irradiation.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41651768.
- Also identified by DOI 10.1021/acs.nanolett.5c04268 and PMC identifier 12922180.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
In layered materials, charge density waves can occur in distinct chiral phases, which can be switched. We use Xe<sup>8+</sup> ions at a kinetic energy of 22.5 keV to switch the commensurate charge density wave chirality on the nanoscale in 1<i>T</i>-TaS<sub>2</sub> at 50 K. Changes in spectral weight, density of states, and band structure are monitored <i>in situ</i> by angle-resolved photoemission spectroscopy. We find that changes in the band structure are most pronounced at the charge density wave gaps and that chirality switches gradually with ion fluence, saturating to near-full handedness reversal at ≳4000 ions/μm<sup>2</sup>. We discuss a scenario for ion-induced chiral switching within the framework of intense, spatially confined electronic excitations, which induce a phase transition and defect-stabilized grain boundaries.