Single-Nanoparticle Plasmon-Driven Phase Engineering of Two-Dimensional MoTe<sub>2</sub>.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41666319.
- Also identified by DOI 10.1021/acs.nanolett.5c06230.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
All-optical control of material phases at the nanoscale enables reconfigurable platforms for sensing and nanophotonics. We present a plasmon-driven strategy to both write and read localized 2H→1T' phase transitions in few-layer MoTe<sub>2</sub> using individual Au nanoparticles as dual-function nanoantennas. Their localized surface plasmon resonances concentrate continuous-wave laser excitation to drive the transition via hot carriers and local heating, reducing the threshold power by nearly an order of magnitude, while their dark-field scattering spectra provide <i>in situ</i> optical readout through characteristic redshift-then-blueshift behavior. Raman spectroscopy confirms formation of the 1T' phase. The Au NP/1T'-MoTe<sub>2</sub> system shows a strong temperature-dependent scattering response, enabling nanoscale optical thermal sensing. In an Au/MoTe<sub>2</sub>/MoS<sub>2</sub> vertical heterostructure, plasmon-induced 2H→1T' conversion reconfigures the band alignment, turning a photoluminescence-quenched OFF state into a trion-dominated ON state. This establishes a general route for all-optical, nanoscale phase engineering of 2D materials for active thermal and excitonic control.