Constructing scalable hydrophobe-water micro-interfaces for catalyst-free generation of H<sub>2</sub>O<sub>2</sub> via macroporous resins.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41680139.
- Also identified by DOI 10.1038/s41467-026-69085-w and PMC identifier 13009372.
- Licence recorded as CC BY-NC-ND.
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Abstract
Catalyst-free production of H<sub>2</sub>O<sub>2</sub> at hydrophobe-water micro-interfaces provides a sustainable synthesis route, yet its scalability remains challenging. We demonstrate that hydrophobic macroporous resins (MPRs) can serve as robust, metal-free platforms to construct scalable hydrophobic solid-water interfaces for continuous H<sub>2</sub>O<sub>2</sub> generation, achieving a mass-normalized production rate of H<sub>2</sub>O<sub>2</sub> as ~0.51 μmol g<sub>MPR</sub><sup>-1</sup> h<sup>-1</sup> and eventually ~1 mM-level accumulation of H<sub>2</sub>O<sub>2</sub> after one week's stirring of the resin suspension under ambient atmosphere. Both macroporosity and hydrophobicity of MPRs are essential for the activity, and scale-up 1000 mL confirms practical feasibility. Mechanistic studies indicate that H<sub>2</sub>O<sub>2</sub> forms predominantly via the oxygen reduction reaction (ORR), optimally at pH 9. This process requires no external light or electrical energy input, exhibits high salt tolerance, and is potentially compatible with renewable power sources. This work exemplifies how porous materials can enable sustainable, scalable chemical synthesis and updates the fundamental understanding of the micro-interface reactivity.