Optimal choice of proxy for cloud condensation nuclei reduces uncertainty in aerosol-cloud-climate forcing.

Jia, Hailing; Quaas, Johannes; Kroese, Willem; van Diedenhoven, Bastiaan; Gryspeerdt, Edward; Böhm, Christoph; Block, Karoline; Hasekamp, Otto · Sci Adv · 2026

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Abstract

Aerosol-cloud interactions (ACI) remain the largest uncertainty in anthropogenic climate forcings. Observation-based estimates of instantaneous radiative forcing from ACI (RF<sub>aci</sub>; the Twomey effect) rely on the choice of aerosol quantities as proxies for cloud condensation nuclei (CCN) concentrations, which differ in their ability to represent cloud-base CCN and data accuracy. Using diverse observations and aerosol-climate models, we evaluate the utility of different proxies with two independent approaches. Both approaches reveal that surface CCN exhibits the smallest bias in predicting RF<sub>aci</sub> (+5%), followed by aerosol index, surface sulfate and column CCN with similar biases of +25%, while aerosol optical depth and column sulfate show the largest biases (-60% and +92%). Constraining RF<sub>aci</sub> with the optimal proxy reduces uncertainty from 66 to 43%, yielding a less negative RF<sub>aci</sub> (-1.0 W m<sup>-2</sup>) than the unconstrained case (-1.2 W m<sup>-2</sup>). Our findings highlight the crucial role of proxy constraint in reconciling and improving RF<sub>aci</sub> estimates.