Soft photo-ionotronics.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41723147.
- Also identified by DOI 10.1038/s41467-026-69427-8 and PMC identifier 13039204.
- Licence recorded as CC BY-NC-ND.
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Abstract
The ability to control the movement of charged species in the circuitry of living beings and machines is essential for complex signal processing, computation, and, ultimately, higher functionality. We describe a class of photo-ion generators (PIGs) based on non-ionic photoacids that can create large (> 1000x) irreversible changes in ionic conductivity under illumination, depending on the PIG species, concentration, and solvent. Incorporation of PIGs into elastomers by simple swelling methods yields soft (60 kPa ≤ E ≤ 10 MPa), stretchable, photo-ionic gels (PIGels). The resolution of photo-patterned conductivity in PIGels is less than 1 cm and demonstrates stability over several days, suggesting utility in engineered devices. Leveraging the photo-responsive properties of these materials, we demonstrate high-sensitivity mechanical sensors via conductance changes ([∆G/G<sub>0</sub>]/σ = 20 MPa<sup>-1</sup>) and photo-writable, soft circuitry.