The key role of nanoparticle concentration gradient in aerosol initial growth.

Abstract

New particle formation has been estimated to produce more than half of the global cloud condensation nuclei and profoundly impacts clouds, climate, and air quality. The initial growth from the cluster size ( ~ 1 nm) to a few nanometers, for which the underlying mechanisms can be very different from the subsequent growth, is the most critical stage for new particles to become climate-relevant. However, initial growth mechanisms evidenced by controlled laboratory experiments can rarely explain observations from the real atmosphere. Here we show that a large nanoparticle concentration gradient in the size space can drive unexpected rapid initial growth based on measurements across the globe. It accelerates the condensation of globally abundant oxygenated organic molecules onto a population of new particles compared to a single particle, and substantially increases the fraction of new particles that survive to climate- and air-quality-relevant sizes. Our findings provide insights into explaining the puzzle of the frequent new particle formation events in polluted urban environments and indicate an even more important role of new particle formation in climate predictions.