Morphological changes in smectic liquid crystal microstructures.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 41925320.
- Also identified by DOI 10.1039/d6sm00042h and PMC identifier 13045658.
- Licence recorded as CC BY.
- The licence permits redistribution, so the abstract is shown in full and the full text is available from the publisher.
Abstract
We report temperature-induced morphological transitions of smectic liquid crystal (LC) microstructures from fibers to disc- and umbrella-like structures. We used two systems based on 4-cyano-4'-<i>n</i>-octyloxybiphenyl (8OCB): an 8OCB/decanol system and an 8OCB/cetyltrimethylammonium bromide (CTAB) system. In both systems, LC fiber structures grew from the droplets upon cooling. The LC fiber structures in both systems underwent similar morphological transitions into umbrella-like structures <i>via</i> an intermediate disc-like structure. Furthermore, we observed that repeated temperature cycling induced reversible morphological transitions between umbrella- and disc-like structures. We developed a simple free-energy model, based on elastic and topological defect energies, that explains these morphological changes. These findings suggest design principles for stimuli-responsive smectic LC microstructures and may provide physical insight into the deformation of phase-separated, membraneless organelles.