Lower-mantle iron heterogeneity constrained by the electrical conductivity of Al-bearing bridgmanite.

Han, Kui; Özaydın, Sinan; Fei, Hongzhan; Man, Lianjie; Wang, Fei; Chanyshev, Artem; Withers, Anthony C; Grayver, Alexander et al. · Sci Adv · 2026

basic_science · Level V

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Abstract

Iron distribution in Earth's lower mantle profoundly influences planetary evolution by regulating mineral density and mantle dynamics but remains poorly constrained due to trade-offs between temperature and composition in seismic interpretations. Here, we resolve this challenge by measuring electrical conductivity of Al-, Fe-bearing bridgmanite, the dominant lower-mantle mineral, as a function of iron content (<i>X</i><sub>Fe</sub>) under conditions reaching 2000 K and 27 GPa. Bridgmanite conductivity increases dramatically with <i>X</i><sub>Fe</sub> following an <i>X</i><sub>Fe</sub><sup>3.6</sup> power law, while showing minimal temperature dependence. This pronounced sensitivity enables direct inference of global iron variation from geomagnetic-derived conductivity models. Our analysis reveals iron enrichment in large low-shear velocity provinces, supporting their thermochemical rather than purely thermal nature. We identify extensive high-iron regions beneath the western Pacific extending below 1000 km, indicating a vast basaltic reservoir of subducted oceanic crust. These findings provide independent constraints on Earth's chemical composition and evolution.