The actual Co(10-12) surface structure and CO activation.
basic_science · Level V
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- Record sourced from PubMed, PMID 42140975.
- Also identified by DOI 10.1038/s41467-026-73224-8.
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Abstract
The hexagonal close-packed Co(10-12) surface has two atomic arrangements. The Co(10-12)-A termination, featuring sevenfold, eightfold, and elevenfold coordinated Co atoms, has been predominantly adopted in previous studies, based on a low-energy electron diffraction (LEED) intensity/voltage study of a Co(10-12) single crystal. Herein, we show that subsurface oxygen species (O<sub>sub</sub>) in Co(10-12) single crystal, hardly removed by the routine method of ion sputtering followed by annealing, affects the LEED spot intensity profile. Via a strategy of H<sub>2</sub>-induced segregation of O<sub>sub</sub> followed by ion sputtering and annealing, a O<sub>sub</sub>-free clean Co(10-12) surface is prepared and exhibits the Co(10-12)-B termination with sevenfold, ninefold, and tenfold coordinated Co atoms. Direct CO activation is much favored than H-assisted CO activation on Co(10-12)-B surface, different from previous reports on Co(10-12)-A surface. Thus, relevant fundamental understanding of Fischer-Tropsch synthesis on Co catalysts previously acquired using Co(10-12)-A surface needs to be reconsidered using Co(10-12)-B surface.