Tailoring crystallization kinetics for scalable and efficient large-area perovskite light-emitting diodes.
basic_science · Level V
Where this comes from
- Record sourced from PubMed, PMID 42234746.
- Also identified by DOI 10.1126/sciadv.aef3336.
- No licence information is recorded for this record.
- Because redistribution is not established, this page shows the abstract only. Follow the links below for the full text.
Abstract
Scalable fabrication of uniform perovskite films is a critical bottleneck for large-area perovskite light-emitting diodes (PeLEDs), hindered by coffee-ring formation and heterogeneous crystallization upon scaling. Here, we report a multimodal solvent-engineering strategy enabling highly uniform films via ambient blade coating combined with vacuum-assisted solvent evaporation. Incorporating <i>N</i>-methyl-2-pyrrolidone (NMP) and acetonitrile (ACN) into a dimethylformamide (DMF)-based system synergistically modulates evaporation dynamics: It suppresses macroscopic solute segregation through Marangoni flow-induced redistribution, while tuning precursor coordination to regulate nucleation/phase conversion and promote radiatively efficient film formation. Consequently, the ternary formulation yields films with improved uniformity, reduced trap densities, and enhanced radiative efficiency. Near-infrared (NIR) PeLEDs achieve peak external quantum efficiencies of 25.2% (10 mm<sup>2</sup>), 22.1% (60 mm<sup>2</sup>), and 19.0% (224 mm<sup>2</sup>). A functional vein-imaging prototype is also demonstrated using a 224-mm<sup>2</sup> device, highlighting the impact for large-area optoelectronic applications.