Soft matter, hard rules: Emulsions follow the laws of granular suspension rheology.
basic_science · Level V
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- Record sourced from PubMed, PMID 42616787.
- Also identified by DOI 10.1073/pnas.2611013123.
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Abstract
The flow of dense emulsions underlies applications from food and pharmaceutical processing to bioengineering, yet their rheology remains difficult to interpret under conventional volume-imposed conditions. Here, we change the control variable to osmotic-pressure using a recently developed instrument-the Capillarytron. This approach reveals a unified rheological structure where the osmotic pressure [Formula: see text], by controlling droplet deformation, sets a <i>pressure-dependent</i> jamming volume fraction. When expressed in terms of the distance to this jamming point, all rheological data-spanning both [Formula: see text]- and [Formula: see text]-imposed measurements-collapse onto a single power-law divergence, akin to granular suspensions. The resulting constitutive relations provide a predictive, parameter-free description of emulsion rheology across Newtonian, yielding, and shear-thinning regimes. Together with recent results on soft spheres, our findings point to a unifying paradigm: Soft amorphous materials-from soft spheres to emulsions and likely foams-obey the same <i>hard rules</i> as granular suspensions, with softness entering through a pressure-dependent jamming point. This framework rationalizes Herschel-Bulkley rheology, assigns its parameters microscopic meaning, and opens perspectives on rigidity transitions in soft, deformable systems, including biological tissues.