Conformational Elasticity at the Buried Interface: 26.89% Perovskite Solar Cells and 23.95% Certified Modules.
basic_science · Level V
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- Record sourced from PubMed, PMID 42631378.
- Also identified by DOI 10.1002/adma.74771.
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Abstract
Conventional self-assembled monolayers (SAMs) are conformationally rigid. They cannot buffer interfacial strain during rapid perovskite crystallization, limiting both film quality and device stability. We introduce a conformational engineering strategy using 2-benzhydrylidene-succinic acid (BSA), a rigid diphenylmethylene anchor with flexible succinic acid chains to create an elastic buried interface. Atomic simulations show BSA acts as a compressible buffer, delaying stress accumulation by ∼6 Å under displacement. This dynamic strain dissipation improves heterojunction contact and enhances hole extraction and transport. BSA-modified p-i-n devices reach 26.89% (0.045 cm<sup>2</sup>, certified 26.52%). Large-area modules (22.95 cm<sup>2</sup>) deliver 24.30% (certified 23.95%), which is among the highest certified values for this area. The devices retain 90% of initial efficiency after 316 h of diurnal cycling and 88% after 300 extreme transient thermal shock cycles from -20 °C to 100 °C. This conformational design integrates mechanical compliance with electronic functionality in scalable perovskite photovoltaics.