Further studies on the plasma-sprayed amorphous phase in hydroxyapatite coatings and its deamorphization.

Abstract

Plasma-sprayed hydroxyapatite coatings contain a quite large amount of amorphous phase. Infrared analysis shows that the plasma-sprayed amorphous phase is an oxyapatite and the coating predetermined as a hydroxyapatite is proved to be an oxyhydroxyapatite with a small quantity of hydroxyapatite. Heat treatment promotes the transformation of amorphous oxyapatite into a crystalline hydroxyapatite structure and reduces the dissolution rate of the coatings. Further studies focus on the properties of the amorphous phase, showing that amorphous oxyapatite is more soluble in 0.15 M lactic acid at 25 degrees C and that water molecules can accelerate the amorphous/crystalline transformation of the hydroxyapatite structure during the plasma-spraying process.