Gadolinium(III) texaphyrin: a tumor selective radiation sensitizer that is detectable by MRI.

Young, S W; Qing, F; Harriman, A; Sessler, J L; Dow, W C; Mody, T D; Hemmi, G W; Hao, Y et al. · Proc Natl Acad Sci U S A · 1996

basic_science · Level V

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Abstract

Gadolinium(III) texaphyrin (Gd-tex2+) is representative of a new class of radiation sensitizers detectable by magnetic resonance imaging (MRI). This porphyrin-like complex has a high electron affinity [E1/2 (red.) approximately = -0.08 V versus normal hydrogen electrode] and forms a long-lived pi-radical cation upon exposure to hydrated electrons, reducing ketyl radicals, or superoxide ions. Consistent with these chemical findings, Gd-tex2+ was found to be an efficient radiation sensitizer in studies carried out with HT29 cells in in vitro as well as in in vivo single and multifraction irradiation studies with a murine mammary carcinoma model. Selective localization of Gd-tex2+ in tumors was confirmed by MRI scanning.

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