Adsorption from a one-dimensional lattice gas and the Brunauer-Emmett-Teller equation.

Hill, T L · Proc Natl Acad Sci U S A · 1996

basic_science · Level V

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Abstract

An exact treatment of adsorption from a one-dimensional lattice gas is used to eliminate and correct a well-known inconsistency in the Brunauer-Emmett-Teller (B.E.T.) equation-namely, Gibbs excess adsorption is not taken into account and the Gibbs integral diverges at the transition point. However, neither model should be considered realistic for experimental adsorption systems.

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